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The 2021 #NobelPrize in Chemistry has been awarded to Benjamin List and David W.C. MacMillan “for the development of asymmetric organocatalysis.” pic.twitter.com/SzTJ2Chtge— The Nobel Prize (@NobelPrize) October 6, 2021
“অ্যাসিম্যাট্রিক অর্গানোক্যাটালাইসিস” (i) নামে পরিচিত অণু তৈরির জন্য একটি নতুন পদ্ধতি বিকাশে তাদের কাজের জন্য তাদের এ বছর রসায়নে নোবেল পুরস্কার প্রদান করা হয়। অণু তৈরি একটি কঠিন ব্যাপার। তারা অর্গানোক্যাটালাইসিস প্রক্রিয়ার এক নতুন টুল আবিষ্কার করেছেন। ডেভিড ম্যাকমিলান এবং বেঞ্জামিন লিস্টের নোবেল বিজয় সম্পূর্ণ বিস্ময়কর না হলেও তারা বিজ্ঞানমহলের মানুষের ধারণা করার তালিকার শীর্ষে ছিল না। তাদের আরিষ্কারটা যদিও দুই দশকেরও বেশি পুরোনো। ম্যাকমিলান এবং লিস্টের কাজ অর্গানোক্যাটালাইসিসে একটি নতুন দুয়ার খুলতে সাহায্য করেছে। এই প্রযুক্তি ওষুধ শিল্প থেকে থেকে শুরু করে সৌর কোষের রঞ্জক সহ অনেক ক্ষেত্রেই প্রয়োগ করা হয়েছে এবং এটি রসায়নকে সবুজ করে তুলেছে। রসায়নের নোবেল কমিটির চেয়ারম্যান জোহান একুইস্ট বলেন, “ক্যাটালাইসিসের জন্য এই ধারণাটি যতটা সহজ, ততটা অসাধারণ। কেন আমরা এই সহজ আর কার্যকরী পদ্ধতি আগে ভাবিনি!” একটা জিনিস মানুষ আজ নিশ্চয়ই বলবে না, “এটা চমৎকার, কিন্তু এটা কি রসায়ন?”
অনেক গবেষণার ক্ষেত্র এবং শিল্প, রসায়নবিদদের ডেভেলপ করা অণু তৈরির ক্ষমতার উপর নির্ভরশীল যেটা স্থিতিস্থাপক এবং শক্তিশালী উপকরণ তৈরি করতে পারে। যেটি ব্যাটারিতে শিল্পে শক্তি সঞ্চয় করতে পারে আবার রোগ নির্ণয় এবং নিয়ন্ত্রণ সেক্টরের রোগের অগ্রগতি রোধ করতে সাহায্য করতে পারে নতুন নতুন অনু তৈরি সহজতর করে। এই কাজের জন্য অনুঘটক (catalyst) প্রয়োজন যা মুলত এক ধরণের পদার্থ যা চূড়ান্ত উৎপাদেন অংশ না হয়ে রাসায়নিক বিক্রিয়াগুলিকে নিয়ন্ত্রণ করে এবং ত্বরান্বিত করে। উদাহরণস্বরূপ, গাড়িতে থাকা অনুঘটক নির্গত ধোঁয়ায় বিষাক্ত পদার্থকে নিরাপদ অণুতে রূপান্তরিত করে। আমাদের দেহে এনজাইমের আকারে হাজার হাজার অনুঘটক রয়েছে, যা জীবনের জন্য প্রয়োজনীয় অণুগুলিকে ভাঙ্গতে সাহায্য করে।
অনুঘটক রসায়নবিদদের জন্য একটি মৌলিক হাতিয়ার, কিন্তু গবেষকরা দীর্ঘদিন ধরে বিশ্বাস করতেন যে, নীতিগতভাবে, কেবলমাত্র দুই ধরণের অনুঘটক ছিল: ধাতু এবং এনজাইম। বেঞ্জামিন লিস্ট এবং ডেভিড ম্যাকমিলান ২০২১ সালে রসায়নে নোবেল পুরস্কার পান কারণ ২০০০ সালে তারা পৃথক হয়ে তৃতীয় এক ধরণের ক্যাটালাইসিস বা অনুধটক তৈরি করেছিলেন। এটিকে ‘অ্যাসিম্যাট্রিক অর্গানোক্যাটালাইসিস’ বলা হয় এবং এই অনুধটক ছোট জৈব অণুর উপর ভিত্তি করে তৈরি হয়।
জৈব অনুঘটকে কার্বন পরমাণুর একটি স্থিতিশীল কাঠামো রয়েছে, যার সাথে অন্যান্য আরও সক্রিয় রাসায়নিক অনু সংযুক্ত হতে পারে। এগুলোতে সাধারণ অক্সিজেন, নাইট্রোজেন, সালফার বা ফসফরাসের মতো সাধারণ উপাদান থাকে। এর অর্থ এই যে এই অনুঘটকগুলি পরিবেশবান্ধব এবং উৎপাদনে খরচ তুলনামূলক অনেক কম।
অনুঘটক কেন খুবই গুরুত্বপূর্ণ তা উপরে আলোচনা করে হয়েছে। এখন জৈব অনুঘটক ব্যবহারের হার দ্রুত সম্প্রসারিত হচ্ছো এর কারণ মূলত তাদের অসমমিত ক্যাটালাইসিস চালানোর ক্ষমতা। যখন কোনো অণু তৈরি করা হচ্ছে, এমন পরিস্থিতি প্রায়ই ঘটে যেখানে দুটি ভিন্ন অণু তৈরি হতে পারে, যা – আমাদের হাতের মতো – একে অপরের মিরর ইমেজ। রসায়নবিদরা প্রায়শই এইগুলির মধ্যে একটি চান, বিশেষত যখন ওষুধ উৎপাদন করে।
২০০০ সাল থেকে অর্গানোক্যাটালাইসিস একটি বিস্ময়কর নতুন দুয়ার বিকশিত করেছে। এই প্রতিক্রিয়াগুলি ব্যবহার করে, গবেষকরা এখন আরও দক্ষতার সাথে নতুন ফার্মাসিউটিক্যালস থেকে শুরু করে এমন অণু তৈরি করতে পারেন যা সৌর কোষে আলো ধরতে পারে। এইভাবে, অর্গানোক্যাটালিস্ট মানবজাতির জন্য সবচেয়ে বড় সুবিধা নিয়ে আসছে। আর নোবেল পুরষ্কার যেহেতু মানব কল্যানে অবদান রাখার জন্য দেয়া হয়ে থাকে। তো বলার অপেক্ষা রাখে না যে এটা দুই দশক ধরে মানব কল্যানে ব্যবহুত হয়ে আসছে।
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“คาสิโน” คือ บ่อนการพนันขนาดใหญ่ ที่มีเกมการพนันหลากหลายรูปแบบไว้คอยบริการ เมื่อนึกถึง “คาสิโน” เราสามารถจินตนาการถึงมันได้สัก 3 รูปแบบ สหรัฐอเมริกาประกอบด้วย 50 รัฐซึ่งแบ่งออกเป็นมณฑลและแบ่งออกเป็นเมืองเล็ก ๆ และเขตเทศบาล วอชิงตัน ดี.ซี. ไม่ใช่รัฐ แต่มีกฎหมายของตนเองซึ่งใช้เฉพาะกับเมืองนี้เท่านั้น
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